ArticleACS omega2025
Influence of Charge Compensating Anions on the Adsorption of Perfluorobutanesulfonate in MOF-808.
Article in ACS omega, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
9 authors.
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Abstract
Per- and poly fluoroalkyl substances (aka PFAS) are a class of anthropogenic compounds that have come under scrutiny given their ability to bioaccumulate in the environment and negatively impact health outcomes. Metal-organic frameworks (MOFs) are an emerging category of sorbents that are attractive for PFAS remediation given their readily modifiable nature. Here we show that the charge compensating anions (cca's) formate (FA), acetate (AA), trifluoroacetate (TFA), and chloride have a significant impact on the adsorption of perfluorobutanesulfonate (PFBS) within MOF-808. Kinetic measurements indicate that MOF-808 rapidly adsorbs PFBS with equilibrium reached within 50 min or less. The kinetic data is well-fit to the pseudo first-order Langmuir model and the resultant pseudo first-order rate constants vary by a factor of 4 (0.16-0.61 min
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