ArticleBiomaterials and biosystems2025
Development of biodegradable Fe-Mn thin structures by electroforming in deep eutectic solvents.
Article in Biomaterials and biosystems, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Fe-Mn alloys represent promising candidates for temporary biomedical intravascular implants with a thin structure (e.g., coronary, cerebral and peripheral stents) due to their high mechanical strength, acceptable biocompatibility, and controllable corrosion rate. Traditionally, these devices are produced by casting followed by thermo-mechanical processing, i.e. a time- and energy-intensive top-to-bottom approach. This study explores electroforming as an alternative method to fabricate bottom-to-top thin Fe-Mn structures using ethylene glycol-based deep eutectic solvents (DESs). Glycine was introduced as a complexing agent to enhance Mn co-deposition. Electroforming was investigated in presence of three glycine concentrations (0.2, 0.4, and 0.6 M), and the the microstructure, composition, corrosion behavior, and cytocompatibility of the developed thin (50-85 µm) structures were characterized. Higher glycine content improved Mn incorporation, crystallinity, hardness and increased corrosion rate. These findings support the use of DES-based electroforming as a promising route for fabricating biodegradable Fe-Mn devices with tunable properties.
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