ArticleChemical communications (Cambridge, England)2025
Photo-induced ruthenium-catalyzed alkene C-H-arylation at room temperature.
Article in Chemical communications (Cambridge, England), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
C-H arylation has surfaced as a powerful tool for molecular sciences, with alkene C-H arylation thus far requiring either high reaction temperatures of 120 °C or stoichiometric amounts of RMgX. In sharp contrast, we herein report on room-temperature C-H arlyations of alkenes by means of ruthenium(II) catalysis with ample scope. This strategy also enabled late-stage diversification of structurally complex molecules and mechanistic studies provided strong evidence for photo-excitation of a ruthenacycle intermediate.
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