ArticleAngewandte Chemie (International ed. in English)2025
Isolation of Anionic N-Heterocyclic Olefins and Their Versatile Reactivity.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Azetidinylideneketenimines as a Multimodal Synthetic Platform: Coordination Chemistry and Cycloaddition-Triggered Transformations.Angewandte Chemie (International ed. in English) · 2026Article
- Isolation of Anionic N-Heterocyclic Olefins and Their Versatile Reactivity.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
6 authors.
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Abstract
N-Heterocyclic olefins (NHOs) have emerged as powerful bases and nucleophiles with broad applications in synthesis and catalysis. Here, we report a new synthetic approach to accessing their anionic derivatives through a formal ligand exchange reaction of metalated ylides or diazomethanes with free carbenes. The reaction was found to depend on the nature of the carbene, with more electrophilic carbenes reacting more readily via N
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Registered trials
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