ArticleJournal of the American Chemical Society2025
Paired Pulsed Decarboxylative Hydroxylation Designed by Online Electrochemistry-Mass Spectrometry.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed.
- Direct visualization of inner-sphere electrocatalytic reactions as they occur at detachable electrochemical interfaces.Chemical science · 2026Article
- Floquet States of Chemoselective Alternating Current Electrosynthesis.Journal of the American Chemical Society · 2026Article
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We present a novel strategy for optimizing paired pulsed electrosynthesis by real-time monitoring of redox processes at the electrode interface using voltammetry-electrospray ionization mass spectrometry (VESI-MS). VESI-MS provides molecular insight into interfacial events, enabling the rational design of voltage pulses and synchronization of redox reactions, facilitating the discovery of new alternating current (AC) electrochemical transformations. We apply this approach to develop a selective decarboxylative hydroxylation by coupling oxygen reduction with the oxidative decarboxylation of a carboxylic acid. The pilot study with 2-phenylpropionic acid yields 1-phenylethanol with excellent selectivity using only molecular oxygen, KPF
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Registered trials
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