Evidence map›Paper›PMID 41028933›Full record

ArticleThe Journal of organic chemistry2025

Competing Michael/Anti-Michael Addition of Silyl Ketene Acetals to β-Nitrostyrenes Incorporating an Electron-Withdrawing Group.

Mayte A Martínez-Aguirre, Diego A Cruz-Aguilar, Eduardo Hernández-Huerta, Dylan López-Barba, Ricardo Ballinas-Indili, Saulo César Rosales-Amezcua, Cecilio Álvarez-Toledano, Marcos Hernández-Rodríguez

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Mayte A Martínez-AguirreInstituto de Química, Universidad Nacional Autónoma de México Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. Mx., México.
Diego A Cruz-AguilarInstituto de Química, Universidad Nacional Autónoma de México Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. Mx., México.
Eduardo Hernández-HuertaInstituto de Química, Universidad Nacional Autónoma de México Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. Mx., México.ORCID 0000-0002-4883-4528
Dylan López-BarbaInstituto de Química, Universidad Nacional Autónoma de México Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. Mx., México.
Ricardo Ballinas-IndiliDepartamento de Ciencias Químicas, Facultad de Estudios Superiores Cuautitlán-UNAM, Campo 1, Avenida 1ro. de mayo s/n, Cuautitlán Izcalli, Estado de México C.P. 54740, México.
Saulo César Rosales-AmezcuaInstituto de Química, Universidad Nacional Autónoma de México Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. Mx., México.ORCID 0009-0001-0452-6638
Cecilio Álvarez-ToledanoInstituto de Química, Universidad Nacional Autónoma de México Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. Mx., México.ORCID 0000-0002-1983-2937
Marcos Hernández-RodríguezInstituto de Química, Universidad Nacional Autónoma de México Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. Mx., México.ORCID 0000-0001-8686-160X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

β-Nitrostyrenes are archetypal Michael acceptors due to the strong electron-withdrawing nature of the nitro group. However, we found that β-nitrostyrenes substituted with electron-withdrawing groups react with silyl ketene acetals, activated by stoichiometric Lewis bases (K

Identifiers

PMID41028933
PMCPMC12519467

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.