Evidence map›Paper›PMID 41028124›Full record

ArticleScientific reports2025

Nd-doped CuO/ZnO and ZnO/CuO heterojunctions for simultaneous UV blocking and malachite green detoxification.

Samir Osman Mohammed, Mostafa M H Khalil, Islam M El-Sewify, Ahmed Radwan

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Article in Scientific reports, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

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3citing papers in PubMed
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1 · What the graph read from it

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2 · The registry

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3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

4 authors.

Samir Osman MohammedPhysics Department, Science Faculty, Ibb University, Ibb, Yemen. samir.qa@just.edu.ye.
Mostafa M H KhalilDepartment of Chemistry, Faculty of Science, Ain Shams University, Abbassia, 11566, Cairo, Egypt.
Islam M El-SewifyDepartment of Chemistry, Faculty of Science, Ain Shams University, Abbassia, 11566, Cairo, Egypt.
Ahmed RadwanDepartment of Chemistry, Faculty of Science, Ain Shams University, Abbassia, 11566, Cairo, Egypt.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A novel two-step wet-chemical synthesis produced neodymium-doped core/shell heterojunctions, Copper(II) oxide (neodymium)/Zinc oxide(CuO(Nd)/ZnO and Zinc oxide (neodymium)/Copper(II) oxide ZnO(Nd)/CuO), with tunable optoelectronic and photocatalytic properties. Structural characterization via x-ray diffraction (XRD) and transmission electron microscopy (TEM) reveals uniform crystallite sizes (6.3-31.4 nanometers- nm) and distinct morphologies: hexagonal for CuO(Nd)/ZnO and spherical for ZnO(Nd)/CuO. Incorporating neodymium induced lattice strain (7.8-10.2 × 10⁻⁴) and increased Urbach energies (5.0-15.3 millielectron volts-meV), enhancing defect states. Tauc analysis demonstrated bandgap narrowing to 2.49-3.17 eV for ZnO and 1.49-1.55 eV for CuO. ZnO(Nd)/CuO achieved a remarkable 94.6% degradation of malachite green (MG) under cost-effective 500 W (W) white light irradiation. This significantly surpasses the performance of undoped systems (by 5%) and generally exceeds that reported for other nanocomposites (≤ 90%) in the literature. Conversely, CuO(Nd)/ZnO exhibited 89.04% ultraviolet blocking efficiency at 280-315 nm (UV-B), outperforming polymethyl methacrylate (PMMA) with ZnO quantum dots (50-60%) and ZnO nanoparticles with polylactic acid composite films (15-75%). These enhancements stem from neodymium(III) (Nd³)-mediated trap states, optimized band alignment, and charge separation at the heterojunction interface. Integrating rare-earth doping with core/shell architecture provides a scalable route for high-performance photocatalytic and ultraviolet-protective materials.

Indexed as

Core(neodymium-doped)/ShellMalachite green removalNano-heterojunctionsUltraviolet blockingUrbach energy

Identifiers

PMID41028124
PMCPMC12484677

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