Degradation effects of reused PA12 powder in selective laser sintering on material characteristics, dimensional accuracy and mechanical strength.

Selective Laser Sintering of Polymers is a widely used Additive Manufacturing technology that involves a laser to selectively sinter layers of a powder bed, with Polyamide 12 being a common material choice. Despite its favourable processability and component performance, the printing process leaves a significant amount of unsintered powder that undergoes heat treatment due to temperature gradients during printing, leading to material degradation over time. A deep comprehension of the aging behaviour in the powder for rightly planning the successive building process is thus necessary to define the proper recycling methods. This paper presents a comprehensive study of the thermal and structural characteristics of Polyamide 12 after five successive reusing cycles, as well as the dimensional accuracy and the mechanical strength of the corresponding printed parts. The study includes tests on the powder that underwent successive printing, and the parts manufactured using this powder. The results were compared to those obtained from virgin powder. These results were used to justify the differences in mechanical, macro-geometrical, and micro-geometrical performance between virgin and multiple reused powder parts. The results indicate that the powder degradation causes a significant reduction of the mechanical strength, and the texture quality of parts made from reused powder, while the dimensional accuracy remains very high.