Evidence map›Paper›PMID 41024695›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Revealing the Active State of a Cu/ZnO:Al Catalyst During Reverse Water-Gas Shift Reaction in an Operando Microwave Absorption Study.

Zohreh Asadi, Clara Patricia Marshall, Annette Trunschke, Thomas Risse

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. The journal of physical chemistry. C, Nanomaterials and interfaces · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Zohreh AsadiInstitute of Chemistry and Biochemistry, Freie Universität Berlin, Arnimallee 22, 14195, Berlin, Germany.ORCID https://orcid.org/0009-0008-2834-7862
Clara Patricia MarshallDepartment of Inorganic Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany.
Annette TrunschkeDepartment of Inorganic Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany.ORCID https://orcid.org/0000-0003-2869-0181
Thomas RisseInstitute of Chemistry and Biochemistry, Freie Universität Berlin, Arnimallee 22, 14195, Berlin, Germany.ORCID https://orcid.org/0000-0003-0228-9189

Funding

Einstein Foundation BerlinEuropean Commission Horizon-EIC 101099273Federal Ministry of Education and Research Germany (BMBF) FKZ 03EW0015B
6 · The paper itself

Abstract

The industrially important Cu/ZnO:Al (CZA) catalyst is known as a dynamic system adapting to reaction conditions, which renders the application of in situ and operando methods key to establish structure function correlations. Herein, a CZA catalyst close to the industrially used compostion was studied using noninvasive and bulk-sensitive in situ/operando microwave cavity perturbation technique and electron paramagnetic resonance spectroscopy during activation and reverse water gas shift reaction. The transient changes of catalytic activity track with the transients of the dielectric properties providing evidence for the importance of bulk properties for catalytic activity. Furthermore, convincing support for the redox reaction mechanism is obtained, and it is shown that H

Indexed as

Cu/ZnO:Al catalystOperando EPR spectroscopyOperando MCPT, Reaction mechanismReverse water—gas shift reaction

Identifiers

PMID41024695
PMCPMC12603976

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.