Evidence map›Paper›PMID 41024385›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Tunable Photoluminescent and Photothermal Properties of Organic Cocrystals Containing Hydrogen-Bonded Interlocked Planar Molecules.

Xinmeng Chen, Ling Zhu, Shan He, Bin Liu, Qiang Lv, Xuedong Wang, Lin Xu, Yu Wang, Ryan T K Kwok, Jacky W Y Lam and 3 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Xinmeng ChenDepartment of Chemistry, and the Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, 999077, China.
Ling ZhuShanghai Key Laboratory of Green Chemistry and Chemical Processes, Shanghai Frontiers Science Center of Molecule Intelligent Syntheses, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200062, China.
Shan HeDepartment of Chemistry, and the Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, 999077, China.
Bin LiuSchool of Chemistry, Sun Yat-Sen University, Guangzhou, 510006, China.
Qiang LvInstitute of Functional Nano & Soft Material (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu, 215123, China.
Xuedong WangInstitute of Functional Nano & Soft Material (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu, 215123, China.
Lin XuShanghai Key Laboratory of Green Chemistry and Chemical Processes, Shanghai Frontiers Science Center of Molecule Intelligent Syntheses, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200062, China.
Yu WangKey Laboratory of Organic Integrated Circuit, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, China.
Ryan T K KwokDepartment of Chemistry, and the Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, 999077, China.
Jacky W Y LamDepartment of Chemistry, and the Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, 999077, China.
Lianrui HuShanghai Key Laboratory of Green Chemistry and Chemical Processes, Shanghai Frontiers Science Center of Molecule Intelligent Syntheses, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200062, China.
Wenping HuKey Laboratory of Organic Integrated Circuit, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, China.
Ben Zhong TangDepartment of Chemistry, and the Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, 999077, China.ORCID https://orcid.org/0000-0002-0293-964X

Funding

Innovation and Technology Commission ITC-CNERC14SC01National Natural Science Foundation of China 52473192Research Grants Council of Hong Kong 16303320Science Technology Innovation Commission of Shenzhen Municipality JCYJ20220818103007014Science Technology Innovation Commission of Shenzhen Municipality KQTD20210811090142053Shenzhen Key Laboratory of Functional Aggregate Materials ZDSYS20211021111400001
6 · The paper itself

Abstract

Expanding the structural diversity of precursor molecules can inject greater vitality into the development of cocrystal engineering. Here, two hydrogen-bond interlocked planar molecules, HNAO and HPAO is reported, which coassemble with 1,2,4,5-tetracyanobenzene (TCB) into charge-transfer (CT) cocrystals NTC and PTC. The resulting NTC inherits two-photon adsorption properties from HNAO, with the bathochromic shift enhanced by synergistic ESIPT and CT interactions, ultimately achieving near-infrared emission. Remarkably, the intramolecular hydrogen bonds lock the molecule into a planar and ordered conformation, enabling regular face-to-face packing in NTC organic microwires and yielding the lowest optical-loss coefficient (0.021 dB/µm) of organic cocrystal to date, thereby demonstrating great potential for applications in optical computing systems. In contrast, the extremely low energy gap between the HOMO of HPAO and the LUMO of TCB in PTC drives a dramatically higher degree of CT in its excited states, predominantly facilitating non-radiative transitions and resulting in non-emissive behavior. Nevertheless, this trade-off enables efficient NIR-I photothermal conversion (η = 47.7%) and excellent photostability, making PTC highly effective for rapid photothermal imaging and breakthrough time-dependent information encryption applications. This work enriches the library of cocrystals and provides a novel strategy for tailoring the properties of cocrystal materials.

Indexed as

charge transfercocrystalluminescencemoleculesphotothermal conversion

Identifiers

PMID41024385
PMCPMC12752575

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.