ArticleSmall (Weinheim an der Bergstrasse, Germany)2025
Air-Insensitive Sulfonylation Enabled by a MOF-Supported Nickel Photocatalyst.
Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
1 citing paper in PubMed.
- Air-Insensitive Sulfonylation Enabled by a MOF-Supported Nickel Photocatalyst.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
Abstract
Photoredox nickel dual catalysis has become a powerful tool in organic synthesis over the past decade, demonstrating versatile reactivity and utilizing earth-abundant metals to form new bonds. However, the requirement for strict inert-gas protection and the existence of intricate metal complex equilibria in homogeneous systems present obstacles to further advancement in practical applications and mechanistic studies. Herein, a heterogeneous strategy is devised by immobilizing nickel complexes within a highly crystalline mesoporous framework, enabling the photoinduced sulfonylation of aryl halides to proceed under ambient air conditions. Notably, pre-treatment with coordinating solvents significantly enhances the activity of the framework-supported nickel catalyst. This research not only broadens the scope of sustainable cross-coupling methodologies but also provides valuable insights into designing robust heterogeneous photocatalytic systems.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.