ArticlePolymers2025
Enhanced Mechanical Robustness of Sprayed Cellulose Nanofibril Coatings Through Internal Crosslinking with Boric Acid.
Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The enhanced mechanical durability of sprayed nanocellulose coatings at the macroscopic level is primarily required to promote their application in demanding industrial applications with frequently exposed surfaces. In this study, different coating configurations are designed by spraying aqueous cellulose nanofiber (CNF) suspensions in combination with boric acid (BA) as an internal crosslinker and polydopamine (PDA) as an adhesive interlayer onto glass substrates. Multilayer coatings (CNF/BA) or mixed-layer coatings (CNF + BA) with various concentrations of BA and numbers of sprayed layers are evaluated for maximized mechanical performance based on tape tests, rub tests, cross-cut tests, and scratching tests. Good adhesive strength was realized with an interlayer of PDA/BA (high-concentration BA = 10 mM). The highest cohesive strength was observed for a mixed CNF + BA coating (high-concentration BA = 10 mM) with a scratch resistance of 9 N, and a multilayer CNF/BA coating (gradient layers with ultra-high BA concentration = 100 mM) with a scratch resistance of 8 N. The coatings with the highest density did not uniquely introduce the best mechanical resistance when comparing CNF/BA and CNF + BA coatings, as the formation of BA crystals in multilayer coatings might negatively affect the mechanical properties through embrittlement. Alternatively, the mixed CNF + BA coatings with high BA concentrations provide high density and the best mechanical resistance. The favorable crosslinking corresponds to stabilized water contact angles and reduced spreading of the water as a function of time, while a decrease in coating density causes a reduction in transparency. The chemical interactions between CNF and BA are illustrated by infrared spectroscopy, confirming a reduction in free hydroxyl groups upon crosslinking.
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