Corrosion Behavior of Biocompatible Ti3Mn Alloy in Different Physiological Conditions for Biomedical Applications.

Titanium-manganese alloys have emerged as a promising option of β-phase titanium alloys, which have recently gained popularity thanks to their exceptional cold strength, deformability, and high specific strength. In this study, the vacuum arc melting process was used to obtain a Ti3Mn alloy, and its behavior in three physiological conditions was analyzed: at room temperature, simulated fever conditions (at 40 °C), and simulated severe infection conditions (pH = 1.2). Optical and scanning electron microscopy were employed to study the effect of Mn addition on the Ti-base alloy microstructure. It was observed the formation of fine precipitates of Mn2Ti, localized at the grain boundaries, allow for the increase in microhardness and blocked their growth. The beta phase of titanium was obtained as fine lamellae with a low level of porosity. The microhardness values were higher than those reported for cp-Ti. The electrochemical tests have shown a high resistance to corrosion in the three analyzed conditions. On the sample's surface, there is a passive bilayer film, composed of a porous one being in contact with the physiological liquid and a compact one in contact with the bulk alloy. The results obtained suggest that Ti3Mn alloy can be a promising low-cost biomaterial for biomedical applications.