ArticleInternational journal of molecular sciences2025
Formation and Structure of Highly Ordered Self-Assembled Monolayers on Au(111) via Vapor Deposition of Dioctyl Diselenides.
Article in International journal of molecular sciences, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The formation and growth processes of octaneselenolate (C8Se) self-assembled monolayers (SAMs) on Au(111) from dioctyl diselenides were investigated by scanning tunneling microscopy (STM) as a function of vapor deposition time at 363 K. STM observations revealed unique surface features of the C8Se SAMs on Au(111) prepared at 363 K for 1 h, consisting of various types of narrow, bright molecular rows and broad, bright molecular rows with three-directional orientations. After increasing the deposition time from 1 and 6 h, interestingly, the structural quality of C8Se SAMs is greatly enhanced, showing the formation of tri-directional highly ordered domains with distinct domain boundaries on an entire Au(111) surface. The observed ordered phase can be described by a (2 × 2√7)rect packing structure with an arial density of 28.9 Å
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