Evidence map›Paper›PMID 41006597›Full record

ArticleNature chemistry2025

Tunable cobalt-catalysed hydrogenation of allenes enabled by multiple metal-ligand cooperative functionalities.

Xianle Rong, Yunjuan Ren, Yongshun Chen, Chongyao Li, Jie Wang, Zhaoqiang Chen, Lizhi Tao, Zhihong Wei, Shengming Ma, Qiang Liu

Abstract read
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In one paragraph

Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Xianle Rong *China Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.ORCID http://orcid.org/0009-0002-8326-4062
Yunjuan Ren *Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Key Laboratory of Energy Storage Materials Innovation and Integration of Shanxi Province, Shanxi University, Taiyuan, China.
Yongshun ChenChina Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.
Chongyao LiChina Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.ORCID http://orcid.org/0000-0003-0872-492X
Jie WangResearch Center for Molecular Recognition and Synthesis, Department of Chemistry, Fudan University, Shanghai, China.ORCID http://orcid.org/0000-0002-7512-4572
Zhaoqiang ChenResearch Center for Molecular Recognition and Synthesis, Department of Chemistry, Fudan University, Shanghai, China.
Lizhi TaoDepartment of Chemistry, Southern University of Science and Technology, Shenzhen, China. taolz@sustech.edu.cn.ORCID http://orcid.org/0000-0001-9921-2297
Zhihong WeiInstitute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Key Laboratory of Energy Storage Materials Innovation and Integration of Shanxi Province, Shanxi University, Taiyuan, China. weizhihong@sxu.edu.cn.ORCID http://orcid.org/0000-0002-9460-7908
Shengming MaResearch Center for Molecular Recognition and Synthesis, Department of Chemistry, Fudan University, Shanghai, China. masm@sioc.ac.cn.ORCID http://orcid.org/0000-0002-2866-2431
Qiang LiuChina Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China. qiang_liu@mail.tsinghua.edu.cn.ORCID http://orcid.org/0000-0002-8402-029X

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22202123National Natural Science Foundation of China (National Science Foundation of China) 22225103
6 · The paper itself

Abstract

Catalytic hydrogenation is essential in synthetic chemistry, with ongoing innovations aimed at enhancing the selectivity and efficiency of these reactions. The hydrogenation of multisubstituted allenes, however, presents a long-standing challenge due to the difficulty of controlling multiple selectivity factors simultaneously. Here we introduce a series of chiral pincer cobalt catalysts featuring multiple metal-ligand cooperative functionalities. These catalysts feature an 'N-H' moiety as an outer-sphere binding site and an N-heterocycle group as a hemilabile basic site, enabling the use of structurally diverse tridentate ligands for selective hydrogenation of functionalized allenes. This design liberates a coordination site for H

Identifiers

PMID41006597

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.