Evidence map›Paper›PMID 41006263›Full record

ArticleNature communications2025

Fe-electrocatalytic deoxygenative Giese reaction.

Longhui Yu, Shangzhao Li, Hiroshige Ogawa, Yilin Ma, Qing Chen, Ken Yamazaki, Yuuya Nagata, Hugh Nakamura

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Copper-catalyzed and Y(OTf)RSC advances · 2026
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Longhui Yu *The Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong SAR, China.
Shangzhao Li *The Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong SAR, China.
Hiroshige Ogawa *The Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong SAR, China.
Yilin MaThe Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong SAR, China.
Qing ChenThe Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong SAR, China.ORCID http://orcid.org/0000-0003-3106-9281
Ken YamazakiOkayama University, Tsushimanaka, Okayama, Japan.ORCID http://orcid.org/0000-0002-2039-4321
Yuuya NagataWPI Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo, Japan. NAGATA.Yuuya@nims.go.jp.ORCID http://orcid.org/0000-0001-5926-5845
Hugh NakamuraThe Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong SAR, China. hnakamura@ust.hk.ORCID http://orcid.org/0000-0001-5475-7883

Funding

Hong Kong University of Science and Technology (HKUST) Start-up funds (Project No. R9820)Research Grants Council, University Grants Committee (RGC, UGC) ECS, HKUST 26302024
6 · The paper itself

Abstract

A redox-neutral Fe-electrocatalytic deoxygenative Giese reaction is reported. Hydroxyl groups are among the most abundant functional groups, and thus, the development of efficient reactions for their conversion has significant importance in medicinal and process chemistry. Here, we present a redox-neutral Giese reaction via anodic oxidation to generate phosphonium ions in combination with a cathodic reduction to yield low-valent Fe-catalysts. This reaction represents a promising example of a redox-neutral reaction using an Fe-catalyst and electrochemistry. The results obtained in this study will facilitate the exploration of a wide range of novel reactions employing this redox cycle in the future.

Identifiers

PMID41006263
PMCPMC12475461

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.