Pore-Discriminative Pervaporation of Xylene Isomers Through In Situ Synthesized MIL-100(In) Membranes.

Jinsuo Yu, Chenyang Jiang, Yanjun Wang, Zemin Li, Yawei Gu, Rujing Hou, Yichang Pan

Abstract read

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Article in Membranes, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Jinsuo YuState Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.

Chenyang JiangState Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.

Yanjun WangState Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.

Zemin LiState Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.

Yawei GuState Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.

Rujing HouState Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.ORCID 0000-0001-7677-3374

Yichang PanState Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.

Funding

Jiangsu Provincial Double-Innovation Doctor Program No. JSSCBS20230115National Natural Science Foundation of China BK20240556

6 · The paper itself

Abstract

Efficient xylene isomers' separation remains a challenge due to their similar kinetic diameter and boiling points, particularly for the separation of the immediate size of meta-xylene (MX). A metal-organic framework (MOF) membrane offers the opportunity to realize the isomers' separation due to the highly tunable pore size and pore environment. Herein, an In-based hierarchic MOF (MIL-100) with a size of 0.77 nm was screened, aiming at the realization for isomer separation through pore size matching. Meanwhile, the polar microenvironment in the MOF channel built through trimesic acid ligands contributes to the higher affinity to the MX relative to the PX. With the equimolar feed mixture of MX/PX, the optimal membrane demonstrated a total flux of 7.6 kg·m

Indexed as

membrane separationmetal–organic frameworkpervaporationxylene isomers

Identifiers

PMID41002896

DOI10.3390/membranes15090261

PMCPMC12471772

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