Evidence map›Paper›PMID 41001658›Full record

ArticleJACS Au2025

Arrested Cooperative Electron Transfer by Stabilization of a Long-Lived Confined Unpaired Electron.

Cheriehan Hessin, Mokhtar Ben Ghanem, Nolwenn Le Breton, Sylvie Choua, Aurélien Moncomble, Laurence Grimaud, Hervé Vezin, Marine Desage-El Murr

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In one paragraph

Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Cheriehan HessinInstitut de Chimie, Université de Strasbourg, OMECA team, UMR CNRS 7177, 4 Rue Blaise Pascal, Strasbourg 67000, France.
Mokhtar Ben GhanemLaboratoire CPCV, Chemistry Department, Sorbonne Université, École Normale Supérieure, PSL University, CNRS, Paris 75005, France.
Nolwenn Le BretonInstitut de Chimie, Université de Strasbourg, POMAM team, UMR CNRS 7177, 4 Rue Blaise Pascal, Strasbourg 67000, France.
Sylvie ChouaInstitut de Chimie, Université de Strasbourg, POMAM team, UMR CNRS 7177, 4 Rue Blaise Pascal, Strasbourg 67000, France.
Aurélien MoncombleUniversité de Lille, CNRS, UMR 8516 - LASIRe - Laboratoire Avancé de Spectroscopie pour les Interactions la Réactivité et l'Environnement, Lille F-59000, France.ORCID https://orcid.org/0000-0002-4362-269X
Laurence GrimaudLaboratoire CPCV, Chemistry Department, Sorbonne Université, École Normale Supérieure, PSL University, CNRS, Paris 75005, France.
Hervé VezinUniversité de Lille, CNRS, UMR 8516 - LASIRe - Laboratoire Avancé de Spectroscopie pour les Interactions la Réactivité et l'Environnement, Lille F-59000, France.ORCID https://orcid.org/0000-0002-7282-2703
Marine Desage-El MurrInstitut de Chimie, Université de Strasbourg, OMECA team, UMR CNRS 7177, 4 Rue Blaise Pascal, Strasbourg 67000, France.ORCID https://orcid.org/0000-0001-5017-4496

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Cooperative multielectron transfer is central to electron storage strategies and small-molecule activation and involves a thermodynamically favored second electron transfer occurring after the first electron transfer. This is the trademark of molecular systems with inverted redox potentials, but it is counterintuitive from an energetic point of view, and the nature of the transient intermediates involved has remained elusive. Using a nickel complex with inverted redox potentials, we show that a weakly coordinating anion (WCA), such as BAr

Indexed as

electron transferinverted potentialsnickel complexesradicalsredox-active ligandsweakly coordinating anions

Identifiers

PMID41001658
PMCPMC12458033

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.