ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
Benzylphosphonic Acid-Engineered Compact Self-Assembled Monolayers for Bifacial Buried Interface Passivation in High-Performance Inverted Perovskite Solar Cells.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Ternary Cooperative Interface With Electronegative Phosphine Bridges Enables Efficient and Stable Inverted Perovskite Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- A Buried Sulfonate Molecular Bridge for Synchronous Charge Transport and Defect Passivation in High-Performance Perovskite Solar Cells.Nano-micro letters · 2026Article
- Spacer Regulation of the Novel Pyrene-Based Tetrapodal Self-Assembled Monolayers for Efficient and Stable Inverted Perovskite Solar Cells and Modules.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Progress on Synergistic Enhancement of Perovskite Solar Cell Efficiency and Stability via Defect Engineering and Carrier Dynamics Optimization.Small methods · 2026Review
- GIWAXS using microbeam applied in halide perovskite films for high spectral resolution and mapping capability.Journal of synchrotron radiation · 2026Article
- Benzylphosphonic Acid-Engineered Compact Self-Assembled Monolayers for Bifacial Buried Interface Passivation in High-Performance Inverted Perovskite Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
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Authors and funding
11 authors.
Funding
Abstract
While [4-(3,6-Dimethyl-9H-carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) self-assembled monolayers (SAMs) enable high-performance inverted perovskite solar cells (PSCs), their sparse coverage on nickel oxide (NiOx) induces heterogeneous interfacial charge distribution at the buried perovskite interface. This increases non-radiative recombination, ultimately limiting device performance. Herein, benzylphosphonic acid (BPPA) is added, a small molecule featuring a phosphonic acid group, into Me-4PACz to construct a co-assembled monolayer (Co-SAM) with enhanced molecular ordering on NiOx. The resulting compact Co-SAM hole transport layer (HTL) simultaneously improves electrical conductivity, hole mobility, and interfacial energy level alignment, facilitating efficient hole injection. Moreover, BPPA's phosphonic acid groups enable bifacial passivation: coordinating NiOx surface defects while chelating uncoordinated Pb
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