ArticleScientific reports2025
Self-supported Ag(0) nanocatalyst derived from Ag(I)-based coordination polymer.
Article in Scientific reports, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A self-supported microsphere heterogeneous catalyst has been developed from a synthesized Ag(I)-imidazole coordination polymer (compound 1), which was subsequently transformed into an Ag(0)-laden coordination polymer (compound 2) through mild reduction with ascorbic acid. It is proposed that during the reduction process, a measurable fraction of silver ions (Ag(I)) undergo in-situ conversion into silver atoms (Ag(0)), forming uniformly distributed Ag(0) nano-clusters within the structural motif of 2. Additionally, some Ag(0) atoms are suggested to retain the coordination environment of their precursor Ag(I) ions within the framework of 2. The Ag(0)-laden microspheres in catalyst 2 exhibited exceptional zero-energy auto-catalytic decomposition of H
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