Evidence map›Paper›PMID 40981601›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Interactional Features of (RO)

Elisabetta Venturin, Rosa M Gomila, Roberta Bertani, Andrea Pizzi, Paolo Sgarbossa, Arun Dhaka, Antonio Frontera, Giuseppe Resnati

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Comparing Homodimer and Homotrimer Noncovalent Complexes Involving Coinage Metals: A Theoretical Perspective.Chemphyschem : a European journal of chemical physics and physical chemistry · 2026
    Article
  2. Article
  3. Interactional Features of (RO)Angewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Elisabetta VenturinDepartment of Chemistry, Materials, Chemical Engineering "Giulio Natta", Politecnico di Milano, via Mancinelli 7, Milano, 20131, Italy.
Rosa M GomilaDepartment of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa, Palma de Mallorca (Baleares), 07122, Spain.ORCID https://orcid.org/0000-0002-0827-8504
Roberta BertaniDepartment of Industrial Engineering, University of Padova, via F. Marzolo 9, Padova, 35131, Italy.ORCID https://orcid.org/0000-0003-3058-7546
Andrea PizziDepartment of Chemistry, Materials, Chemical Engineering "Giulio Natta", Politecnico di Milano, via Mancinelli 7, Milano, 20131, Italy.
Paolo SgarbossaDepartment of Industrial Engineering, University of Padova, via F. Marzolo 9, Padova, 35131, Italy.ORCID https://orcid.org/0000-0002-0938-953X
Arun DhakaDepartment of Chemistry, Materials, Chemical Engineering "Giulio Natta", Politecnico di Milano, via Mancinelli 7, Milano, 20131, Italy.ORCID https://orcid.org/0000-0003-4130-5364
Antonio FronteraDepartment of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa, Palma de Mallorca (Baleares), 07122, Spain.ORCID https://orcid.org/0000-0001-7840-2139
Giuseppe ResnatiDepartment of Chemistry, Materials, Chemical Engineering "Giulio Natta", Politecnico di Milano, via Mancinelli 7, Milano, 20131, Italy.ORCID https://orcid.org/0000-0002-0797-9296

Funding

Ministerio de Ciencia, Innovación y Universidades
6 · The paper itself

Abstract

Tetroxides of Group 4 elements are benchmark catalysts for aldol reactions and oxidation processes, achieving high yields and regio-, diastereo-, and enantioselectivities. Our computational analyses and experimental studies, performed in solution and solid, consistently reveal that these tetroxides form attractive interactions with lone pair compounds exhibiting distinctive σ-hole bond features. We propose naming these novel bondings as titan bonds (TnBs). These new insights into Ti/Zr/Hf tetroxide interactions may significantly aid in designing more effective catalysts with enhanced selectivities.

Indexed as

Group 4 elementsHydrogen bondTitanium catalystsZirconium catalystsσ‐Hole interactions

Identifiers

PMID40981601
PMCPMC12581999

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.