ArticleRSC advances2025
Hydrothermal synthesis of Ag@Zn-salen MOF nanocomposite
Article in RSC advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
8 authors.
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Abstract
Metal-organic frameworks (MOFs) integrated with noble metal nanoparticles offer transformative potential in biosensing, yet bimetal composites face persistent challenges, including inhomogeneous nanoparticle distribution and framework destabilization. Salen-based MOFs, prized for their thermal stability and tunable electronic properties, remain underexplored for bimetal systems despite their catalytic and plasmonic synergies. This study addresses the critical need for a synthesis strategy that ensures the uniform dispersion of plasmonic silver nanoparticles (Ag NPs) within a robust Zn-salen metal-organic framework (MOF) matrix while preserving structural integrity for biomarker detection applications. Conventional one-pot methods for bimetal MOFs often result in Ag NP aggregation (>200 nm) and pore blockage, compromising porosity and active site accessibility-key limitations for biosensor development. A hierarchical Ag@Zn-SalenMOF composite was engineered
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