Evidence map›Paper›PMID 40979877›Full record

ArticleChemical science2025

Pre-synthetic redox control of structure and properties in copper TTFtt coordination polymers.

Ningxin Jiang, Saranya Velliyarat, Chen-Yu Lien, Ha L Nguyen, Jan Hofmann, Jie-Hao Chen, Arun Ramanathan, Alexander S Filatov, Henry S La Pierre, Shrayesh Patel and 3 more

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In one paragraph

Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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5 · Who and what money

Authors and funding

13 authors.

Ningxin JiangDepartment of Chemistry, University of Chicago Chicago Illinois 60637 USA jsanderson@uchicago.edu.
Saranya VelliyaratDepartment of Chemistry, University of Minnesota Minneapolis Minnesota 55455 USA.
Chen-Yu LienDepartment of Chemistry, University of Chicago Chicago Illinois 60637 USA jsanderson@uchicago.edu.
Ha L NguyenDepartment of Chemistry, University of Chicago Chicago Illinois 60637 USA jsanderson@uchicago.edu.ORCID https://orcid.org/0000-0002-4977-925X
Jan HofmannDepartment of Chemistry, Stony Brook University Stony Brook New York 11794 USA.ORCID https://orcid.org/0000-0002-0182-9174
Jie-Hao ChenPritzker School of Molecular Engineering, University of Chicago Chicago Illinois 60637 USA.ORCID https://orcid.org/0009-0006-8843-0639
Arun RamanathanSchool of Chemistry and Biochemistry, Georgia Institute of Technology Atlanta Georgia 30332-0400 USA.ORCID https://orcid.org/0000-0002-1787-7058
Alexander S FilatovDepartment of Chemistry, University of Chicago Chicago Illinois 60637 USA jsanderson@uchicago.edu.ORCID https://orcid.org/0000-0002-8378-1994
Henry S La PierreSchool of Chemistry and Biochemistry, Georgia Institute of Technology Atlanta Georgia 30332-0400 USA.ORCID https://orcid.org/0000-0002-0895-0655
Shrayesh PatelPritzker School of Molecular Engineering, University of Chicago Chicago Illinois 60637 USA.ORCID https://orcid.org/0000-0003-3657-827X
Karena W ChapmanDepartment of Chemistry, Stony Brook University Stony Brook New York 11794 USA.
Jan-Niklas BoynDepartment of Chemistry, University of Minnesota Minneapolis Minnesota 55455 USA.ORCID https://orcid.org/0000-0002-6240-3759
John S AndersonDepartment of Chemistry, University of Chicago Chicago Illinois 60637 USA jsanderson@uchicago.edu.ORCID https://orcid.org/0000-0002-0730-3018

Funding

X-ray Absorption Spectroscopy (XAS) pp.711-759P41GM103393 · NIGMS · STANFORD UNIVERSITY · PI HODGSON, KEITH O · 2012 to 2019
$30.6M
NIGMS NIH HHS P41 GM103393
6 · The paper itself

Abstract

Conductive coordination polymers (CPs) with sulfur-based ligands offer strong metal-ligand interactions and redox tunability, making them promising candidates for electronic applications. Tetrathiafulvalene-2,3,6,7-tetrathiolate (TTFtt) is a particularly attractive ligand. However, its strong metal-ligand covalency leads to rapid irreversible metal coordination, limiting control over structure and morphology. Here, we demonstrate structural control in Cu TTFtt CPs using a pre-synthetic redox control strategy. Two new copper-based CPs, CuTTFtt and Cu

Identifiers

PMID40979877
PMCPMC12447838

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