ArticleNational science review2025
Decrypting the antisolvent-modulating mechanism in localized high-concentration electrolytes.
Article in National science review, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- A bird's-eye view for future ionic thermoelectrics: from ions to products.National science review · 2026Review
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Antisolvents are one of the main components in localized high-concentration electrolytes (LHCEs), which are considered merely as diluents to control the macro properties and preserve the anion-dominated solvation structure, but their role in shaping the micromicelle-like structure and interface chemistry remains poorly understood. Here, we utilize LHCEs with trifluorobenzene isomer as antisolvent to investigate the antisolvent polarity-dependent solvation structure, interface chemistry and Li deposition behavior in lithium metal batteries (LMBs). The 'dragging effect' of antisolvents on anions can alter the solvation environment, correcting the existing micelle-like solvation structure model of LHCEs. Additionally, the interface adsorption of polar antisolvent negatively impacts the formation of solid electrolyte interphase and ion transport dynamics, thereby influencing the Li deposition behavior. The Li deposition/stripping efficiency in ester-based LHCEs using low-polarity antisolvents is enhanced to 98.55%, as evidenced by the Li||LiFePO
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