ArticleACS macro letters2025
Modulation of Depolymerizable Poly(thioether-thioester) Properties in Reversible Covalent Composites.
Article in ACS macro letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
0 citing papers in PubMed.
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We incorporated thiol-functionalized silica particles as macroinitiators for the construction of composites by ring-opening polymerization of thiolactones. A separate photochemical cross-linking step was employed to enhance the stability of the polymer composite material. The thermal and mechanical properties of the materials can be tuned by varying the amount of particles, and a representative formulation could be 3D printed. The polymer composite was depolymerized in the presence of a catalytic amount of thiol and 1,8-diazabicyclo(5.4.0)undec-7-ene (DBU) base to recover substantial amounts of monomer, which were repolymerized and photo-cross-linked to give a material very similar in mechanical properties to the virgin composite. The modular nature of this system and the reliability of the bond-forming and bond-breaking steps suggest that it may prove to be useful as a new type of recyclable plastic.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.