ArticleACS catalysis2025
Mechanistic and Computational Insights into Asymmetric Intramolecular Iron-Catalyzed Nitrene Transfer into Benzylic C─H Bonds.
Article in ACS catalysis, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Dispersion-Enhanced Nitrogen-Centered Photocatalysis of the Direct Hydrogen Atom Transfer.Angewandte Chemie (International ed. in English) · 2026Article
- Asymmetric Hydrogen Atom Transfer.ACS catalysis · 2026Review
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Authors and funding
9 authors.
Funding
Abstract
Chiral, nonracemic amines are valuable synthetic building blocks for diverse bioactive molecules. Asymmetric C─H amination via transition metal-catalyzed nitrene transfer (NT) is a popular strategy to access enantioenriched benzylamines, but many useful chemocatalysts for this transformation are based on precious metals or require elaborate ligands. Iron catalysts supported by simple ligands capable of asymmetric aminations of diverse sulfamates would be valuable but are surprisingly rare. Herein, we study features of the asymmetric iron-catalyzed NT of homo- and bis-homobenzylic sulfamates to better understand why the development of such reactions has proven challenging. Diverse parameters were examined, including ligand, iron source, oxidant, additive, and solvent. Reactions of the preoxidized iminoiodinane revealed some unexpected relationships between the p
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