Evidence map›Paper›PMID 40964952›Full record

ArticleSmall (Weinheim an der Bergstrasse, Germany)2025

Mechanochemically Synthesized Covalent Organic Framework Effectively Captures PFAS Contaminants.

Maroof Arshadul Hoque, Thomas Sommerfeld, Jan Lisec, Prasenjit Das, Carsten Prinz, Christian Heinekamp, Tomislav Stolar, Martin Etter, David Rosenberger, Janine George and 2 more

Abstract read
In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Maroof Arshadul HoqueBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.ORCID https://orcid.org/0009-0006-9102-3129
Thomas SommerfeldBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.
Jan LisecBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0003-1220-2286
Prasenjit DasDepartment of Chemistry, Functional Materials, Technical University Berlin, Hardenbergstraße 40, 10623, Berlin, Germany.
Carsten PrinzBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0001-8586-5430
Christian HeinekampBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.
Tomislav StolarBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-9824-4462
Martin EtterDeutsches Elektronen-Synchrotron (DESY), Notkestraße 85, 22607, Hamburg, Germany.ORCID https://orcid.org/0000-0002-5183-3585
David RosenbergerBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.
Janine GeorgeBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0001-8907-0336
Biswajit BhattacharyaBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0003-4138-1287
Franziska EmmerlingBAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0001-8528-0301

Funding

Deutsche Forschungsgemeinschaft 387284271
6 · The paper itself

Abstract

Per- and polyfluoroalkyl substances (PFAS) are persistent environmental contaminants that pose significant health risks, prompting urgent efforts to develop effective removal methods and adsorbers. Covalent organic frameworks (COFs) are metal-free adsorbers with high stability and tunable porosity. A highly crystalline COF is synthesised mechanochemically using 1,3,5-tris(4-aminophenyl)benzene (TAPB) and 1,3,5-triformylbenzene (TFB). The formation dynamics are monitored in real time with time-resolved in situ synchrotron X-ray diffraction. The TAPB-TFB COF demonstrates good efficiency in eliminating PFAS from water. Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) are effectively extracted, and most of the adsorption occurred within the first 10 min. Additionally, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and DFT calculations are employed to elucidate the molecular interactions between PFAS and the COF framework. The rapid and efficient removal of PFAS makes TAPB-TFB COF a promising material for water treatment applications.

Indexed as

adsorptionCOFin situmechanochemistryPFAS

Identifiers

PMID40964952
PMCPMC12590536

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.