ArticleScience advances2025
Defect passivation and crystallization modulation in methylammonium-free wide-bandgap perovskites for all-perovskite tandem solar cells.
Article in Science advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Ternary Cooperative Interface With Electronegative Phosphine Bridges Enables Efficient and Stable Inverted Perovskite Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Performance Enhancement of All-Inorganic CsPbISmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Sulfur-Substituted SAMs Induce Pb─S Antibonding Hybridization for Efficient and Durable Perovskite-Silicon Tandems.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Crystallization Pathway Optimization and High-Index Facet Stabilization for Perovskite Photovoltaics.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Balanced Molecular Interactions with Mild Dipole Moment for Intermediate Suppressing in High Performance Antisolvent-Free Regular α-FAPbIAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- Hard Lewis Base-Driven Crystallization Control for Efficient All-Perovskite Tandem Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Solution-Processed Nickel Oxide as Efficient Hole Transport Layers in Inverted Perovskite Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Chelating Coordination Regulates Perovskite Crystallization and Defect Passivation in Sn-Pb Perovskite Solar Cells.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Robust and Tailored 1D/3D Heterojunction for Efficient and Stable Perovskite Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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Authors and funding
21 authors.
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Abstract
Wide-bandgap (WBG; >1.65 electron volts) perovskites based on iodine-bromine (I-Br) mixed halides are critical components of perovskite-based tandem solar cells (TSCs). However, the uncontrolled crystallization dynamics of Br-rich species lead to reduced grain sizes and high defect densities in WBG perovskite films. Herein, a multifunctional additive 3,4,5-trifluorobenzamide (TFBZ) was introduced to enhance the crystallinity and passivate defects of the methylammonium (MA)-free WBG perovskite films. The TFBZ demonstrates superior passivation capability compared to benzamide, effectively mitigating both iodine vacancies and undercoordinated Pb
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