Evidence map›Paper›PMID 40955693›Full record

ArticleAdvanced materials (Deerfield Beach, Fla.)2026

Solvent-Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers.

Sonia Martínez-Giménez, Alejandro Orellana-Silla, Marta Galbiati, Efrén Navarro-Moratalla, Luca Braglia, Sara Stolfi, José Antonio Real, Víctor Rubio-Giménez, Sergio Tatay, Carlos Martí-Gastaldo

Abstract read
In one paragraph

Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Sonia Martínez-GiménezInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0003-2572-4921
Alejandro Orellana-SillaInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0003-1773-2374
Marta GalbiatiInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0002-6021-5156
Efrén Navarro-MoratallaInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0002-3430-6599
Luca BragliaTASC Laboratory, CNR- Istituto Officina dei Materiali, Trieste, 34149, Italy.ORCID https://orcid.org/0000-0003-0796-3670
Sara StolfiAREA Science Park, Padriciano 99, Trieste, 34149, Italy.ORCID https://orcid.org/0000-0002-4539-3878
José Antonio RealInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0002-2302-561X
Víctor Rubio-GiménezInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0003-1269-5885
Sergio TatayInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0003-0785-866X
Carlos Martí-GastaldoInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980, Spain.ORCID https://orcid.org/0000-0003-3203-0047

Funding

European Union NextGenerationEU PRTR-C17.I1Generalitat Valenciana CIDEIG/2022/32Generalitat Valenciana CISEJI/2023/45Generalitat Valenciana MFA/2022/026Generalitat Valenciana MRR/MFA/2022/063H2020 European Research Council ERC-2021-COG-101043428Ministerio de Ciencia, Innovación y Universidades CEX2019-000919-MMinisterio de Ciencia, Innovación y Universidades PRE2020-092798Ministerio de Ciencia, Innovación y Universidades PRE2022-102790Ministerio de Ciencia, Innovación y Universidades RYC2018-024736-IMinisterio de Ciencia, Innovación y Universidades RYC2021-034609-ISpanish National Plan for Scientific and Technical Research and Innovation EUR2021-121999Spanish National Plan for Scientific and Technical Research and Innovation PID2023-146354NB-C41Spanish National Plan for Scientific and Technical Research and Innovation PID2023-150383OB-I00Spanish National Plan for Scientific and Technical Research and Innovation PID2023-150732NB-I00
6 · The paper itself

Abstract

The controlled generation of defects in crystalline materials is widely used to tune properties for improved performance. This strategy is increasingly applied to metal-organic frameworks (MOFs), where coordination vacancies are commonly introduced in solution by exploiting the reversibility of metal-ligand bonds. Here, an innovative solvent-free approach for defect engineering in MOFs is reported based on the selective thermal removal of neutral volatile linkers. This method enables the generation of metal vacancies across a broad compositional space (0-100%) without requiring counterions, redox adjustments, or oxide formation to balance charge. Using a standard thermogravimetric analyser, the extent of linker sublimation is controlled with high precision and reproducibility. Key design criteria for applying this strategy are identified and validated with the Hofmann-type MOF [Fe(pz){Pt(CN)

Indexed as

coordination vacanciesdefect engineeringFe(II) unsaturated sitesmetal‐organic frameworksthermal linker removalvolatile linkers

Identifiers

PMID40955693
PMCPMC13569052

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.