ArticleMolecules (Basel, Switzerland)2025
Construction of a Highly Stable Water-Based Release Agent via 1:1 Silicone Oil-Cyclotetrasiloxane Synergy.
Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
This study develops a high-performance water-based mold release agent for polyurethane (PU) foaming applications. We demonstrate that incorporating octamethylcyclotetrasiloxane (D4) into a dimethyl silicone oil emulsion (5 vol% fixed concentration) significantly enhances key performance metrics. By systematically varying D4 content (0-15 vol%), we characterize droplet morphology, particle size distribution, contact angle, and viscosity to elucidate the underlying enhancement mechanism. Our findings reveal the following: (i) Optimal emulsion stability: At 5 vol% D4, the mold release agent exhibits a narrow particle size distribution (6-9 μm). (ii) Efficient processing: Film formation completes within 10 min, reducing demolding force and yielding PU foam with defect-free, non-adherent surfaces. (iii) Storage stability: After 60 days in ambient conditions, performance remains unchanged, with no phase separation observed under thermal stress (60 °C) or refrigeration (2-6 °C). This work explores an alternative pathway to mitigate key limitations-slow film formation and poor shelf-life-offering a prototype for next-generation release agents.
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