ArticleJournal of the American Chemical Society2025
Click Heterogenization of Phosphines Furnishes Recyclable Hydroformylation Catalysts that Reproduce Homogeneous Performance.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Circumventing the wettability issue of heterogeneous metal catalysts for solvent-free organic transformations.Nature communications · 2026Article
- [TpyActa crystallographica. Section E, Crystallographic communications · 2026Article
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Authors and funding
4 authors.
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Abstract
Heterogeneous catalysts confer notable practical advantages for large-scale reactions, while homogeneous catalysts permit targeted performance optimization. A rapid and general method for the heterogenization of molecular transition-metal catalysts without loss of performance would thus permit facile translation of optimized homogeneous catalysts into practical heterogeneous catalysts. Here, we show how a wide variety of phosphines carrying anionic substituents can be charge-tethered to the walls of the spacious supercages of a metal-organic framework (MOF) to provide an adaptable heterogeneous ligand set in a single synthetic step. The addition of Co
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