ArticleACS catalysis2025
Bismuth Radical Catalysis: Thermally Induced Intramolecular C(sp
Article in ACS catalysis, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Steric Mapping, Ligand Dynamics, and Cycloisomerization Catalysis with Redox Robust MnOrganometallics · 2026Article
- Reactivity of Diaryl Bismuth Cations toward a Platinum(0) Complex: Oxidative Aryl Transfer.Organometallics · 2026Article
- Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer.Angewandte Chemie (International ed. in English) · 2026Article
- Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand.Journal of the American Chemical Society · 2026Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Bismuth radical chemistry has attracted increased interest in recent years. Here, we report a series of bismuth-manganese complexes that catalyze the intramolecular redox-neutral coupling of alkyl iodides and alkynes under purely thermal conditions. Computational studies support the design of catalyst candidates, aiming to achieve low Bi-Mn bond homolytic dissociation energies. The radical nature of the cyclization reaction was supported by EPR spectroscopic spin trap experiments. This underexplored mode of thermally induced radical reactivity was applied to construct a variety of cyclic vinyl iodide compounds, including drug derivatives.
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Registered trials
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