ArticleChemistry, an Asian journal2026
Sensing Picric Acid with Dinuclear Triazole Chelated Iridium(III) Nanoaggregates: Insights into the AIEE Quenching Process.
Article in Chemistry, an Asian journal, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
We synthesized a mononuclear and two dinuclear Ir(III) complexes with a substituted triazole and two triazolyl bidentate chelators bridged through propyl and m-phenylene linkers, respectively. The complexes exhibit a considerable enhancement in emission intensity upon aggregation. The formation of nanoaggregates was confirmed through dynamic light scattering (DLS) and transmission electron microscopy (TEM) studies. The dinuclear complexes quench aggregation-induced enhanced emission in the presence of trinitrophenol (TNP/Picric Acid: PA) selectively from a batch of nitroaromatics in water, whereas the mononuclear complex is not selective. Therefore, dinuclear complexes were employed to selectively detect the explosive nitroaromatic picric acid (PA) in aqueous solution. For Ir1 and Ir2, the Stern-Volmer quenching constants (K
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