The Right Strap: The Role of Tether Position and Length in Acene Distortion.

Israa Shioukhi, Abhijeet Agrawal, Yinon Deree, Benny Bogoslavsky, Ori Gidron

Abstract read

In one paragraph

Article in Organic letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Israa ShioukhiInstitute of Chemistry and Center for Nanoscience and Nanotechnology, The Hebrew University, Jerusalem 9190401, Israel.

Abhijeet AgrawalInstitute of Chemistry and Center for Nanoscience and Nanotechnology, The Hebrew University, Jerusalem 9190401, Israel.

Yinon DereeInstitute of Chemistry and Center for Nanoscience and Nanotechnology, The Hebrew University, Jerusalem 9190401, Israel.

Benny BogoslavskyInstitute of Chemistry and Center for Nanoscience and Nanotechnology, The Hebrew University, Jerusalem 9190401, Israel.ORCID 0000-0001-9555-170X

Ori GidronInstitute of Chemistry and Center for Nanoscience and Nanotechnology, The Hebrew University, Jerusalem 9190401, Israel.ORCID 0000-0002-7037-0563

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We report how the tether position affects the conformation, rigidity, and (chiro)optical properties in anthracene derivatives. While 1,5- and 1,10-tethers (long and short diagonal tethering, respectively) induce comparable twisting, short diagonal tethered derivatives display greater conformational flexibility, significantly impacting fluorescence and chiroptical behavior. Notably, short and long diagonal octyl-tethered anthracenes exhibit inverse temperature-dependent CD responses attributed to thermally accessible twisted conformers. These findings highlight the critical role of the tether position in the design of functional curved aromatics.

Identifiers

PMID40932108

DOI10.1021/acs.orglett.5c02906

PMCPMC12481544

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.