ArticleJournal of the American Chemical Society2025
Tuning the Lifetimes of Photoinduced Deligation in a Metal-Organic Framework via Linker Functionalization.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Building Chemistry from "Lego" Blocks: Metal-Organic Frameworks after the 2025 Nobel Prize.ACS central science · 2026Review
- Photocatalytic Ammonia Synthesis using Fe-Based MOFs: The Role of Ligand Functionalization.Journal of the American Chemical Society · 2026Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Recently photoinduced dynamic ligation in a metal-organic frameworks (MOFs) was reported, where a long-lived charge-transfer excited state (ca. 30 μs) featuring partial dissociation between the carboxylate linker and metal-based node was probed by time-resolved infrared (TRIR) spectroscopy. The study offers a new mechanistic perspective to evaluate the potential contribution from the excited state molecular configuration to the performance of MOF photocatalysts. In this work, by employing MIL-101(Fe) as the study platform, we have further explored the influence of intramolecular interactions on the stability of relevant excited states and demonstrated the effective tuning of their lifetimes through the incorporation of different functional groups into the system. The correlations between the varied excited state lifetimes and coordination configurations with specific functional groups (-NH
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