ReviewElectrochemical energy reviews2025
Stimulating Efficiency for Proton Exchange Membrane Water Splitting Electrolyzers: From Material Design to Electrode Engineering.
Review in Electrochemical energy reviews, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Defect-Driven Accelerated Reconstruction of Metal-Organic Frameworks Toward High-Performance Anion Exchange Membrane Water Electrolysis.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Confinement of PtSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Tailored Interfacial Coupling in CoPi/PANI@Nickel-Cobalt Phosphide Heterostructure Electrocatalysts for Enhanced Hydrogen Evolution in Alkaline Media.ChemSusChem · 2026Article
- Quenching-Induced Octahedral Fe Vacancies in CoFe Spinel Nanosheets for Boosted Oxygen Evolution.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Atomic-level interface engineering enables efficient and durable acidic hydrogen evolution of osmium at large current densities.Chemical science · 2026Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Proton exchange membrane water electrolyzers (PEMWEs) are a promising technology for large-scale hydrogen production, yet their industrial deployment is hindered by the harsh acidic conditions and sluggish oxygen evolution reaction (OER) kinetics. This review provides a comprehensive analysis of recent advances in iridium-based electrocatalysts (IBEs), emphasizing novel optimization strategies to enhance both catalytic activity and durability. Specifically, we critically examine the mechanistic insights into OER under acidic conditions, revealing key degradation pathways of Ir species. We further highlight innovative approaches for IBE design, including (i) morphology and support engineering to improve stability, (ii) structure and phase modulation to enhance catalytic efficiency, and (iii) electronic structure tuning for optimizing interactions with reaction intermediates. Additionally, we assess emerging electrode engineering strategies and explore the potential of non-precious metal-based alternatives. Finally, we propose future research directions, focusing on rational catalyst design, mechanistic clarity, and scalable fabrication for industrial applications. By integrating these insights, this review provides a strategic framework for advancing PEMWE technology through highly efficient and durable OER catalysts. Graphical Abstract: In order to realize the efficient application of the industrial PEMWEs, material design strategies for stimulating the activity and stability capability of OER electrocatalysts are summarized, including (i) morphology/support effects, (ii) structure/phase engineering, (iii) electronic configuration/interaction. Furthermore, the reaction mechanism is deeply clarified, and electrode engineering and challenges of IBEs in practical PEMWE application are focused.
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