ArticleNature communications2025
Regio- and chemoselective catalytic partial transfer hydrogenation of quinolines by dinuclear aluminum species.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Silicon-Bridged Homocyclopentadienides: Metal-Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes.Angewandte Chemie (International ed. in English) · 2026Article
- Polarity-Directed Synthesis of an Exfoliable 2D Polyoxometalate-Based Metal-Organic Framework for Noble Metal-Free Alkyne Transfer Semi-Hydrogenation.Angewandte Chemie (International ed. in English) · 2026Article
- NHC-Stabilized Early Main Group Species: Reactivity and Emerging Catalysis.ACS catalysis · 2026Review
- Isolable radical cation and dication of dialumene.Nature communications · 2026Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Catalytic reduction of quinolines has gained continuous interest in both academia and industry, providing direct and efficient access to tetrahydroquinolines or 1,2-dihydroquinolines. The catalytic preparation of tetrahydroquinolines has been extensively studied by transition metal complexes. By contrast, the related catalytic synthesis of 1,2-dihydroquinolines remains underdeveloped due to the difficulties in achieving precise control over both chemo- and regioselectivity. Here, we demonstrate a catalytic 1,2-reduction of quinolines using a dinuclear aluminum complex, allowing for the highly selective synthesis of a rich array of 1,2-dihydroquinolines through the combination of bimetallic catalysis and metal-ligand cooperation. These investigations showcase the capacity of main group metal catalysts to achieve reactivities distinct from well-studied transition-metal catalysis.
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Registered trials
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