ArticleAngewandte Chemie (International ed. in English)2025
Dynamics of Metal-Metal Bond Dissociation in Pd-Pd and Ni-Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- NMR of nuclei bound to a paramagnetic metal centre: the case ofChemical science · 2026Article
- Anionic T-Shaped Platinum(0) Pincer Complexes and Platinum(I) Intermediates in Radical Reactions With Alkyl Halides.Angewandte Chemie (International ed. in English) · 2026Article
- Metallophilicity Under Confinement: The Iminopyrrole Cage Promoting the HgInorganic chemistry · 2026Article
- Dynamics of Metal-Metal Bond Dissociation in Pd-Pd and Ni-Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
5 authors.
Funding
Abstract
Dinuclear M(I)-M(I) complexes (M = Ni, Pd) may serve as stable reservoir forms for highly reactive mononuclear metalloradicals, which are of interest as potential catalytic species. However, their dissociation dynamics as well as the factors governing monomer stabilization remain incompletely understood. This study investigates the influence of steric bulk and residual ligand flexibility within a PNP pincer framework on the homolytic dissociation behavior of unsupported Ni(I)-Ni(I) and Pd(I)-Pd(I) dimers. Utilizing an
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