Evidence map›Paper›PMID 40904284›Full record

ArticleOrganic letters2025

Structurally Flexible (Thiazol-2-ylidene)Pd(Allyl)Cl Complexes for Suzuki-Miyaura Cross-Coupling of Aryl Halides and Amides.

Ruihong Wang, Xiaoxia Han, Jin Zhang, Nana Chen, Li Sun, Gaopeng Zhang, Michal Szostak

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Organic letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Ligand-Enabled Hydrohydrazidation of Alkynes Catalyzed by Unsymmetrical Gold(I)-Thiazol-2-ylidenes.Organic chemistry frontiers : an international journal of organic chemistry · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Ruihong WangSchool of Food Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
Xiaoxia HanCollege of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
Jin ZhangCollege of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.ORCID 0000-0002-6616-7087
Nana ChenCollege of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
Li SunCollege of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.
Gaopeng ZhangDepartment of Chemistry, Rutgers University, Newark, New Jersey 07102, United States.
Michal SzostakKaili Catalyst & New Materials Co., LTD, Shaanxi Key Laboratory of Catalytic Materials and Technology, Xi'an 710299, China.ORCID 0000-0002-9650-9690

Funding

Catalytic Methods for Organic SynthesisR35GM133326 · NIGMS · RUTGERS THE STATE UNIV OF NJ NEWARK · PI Michal Szostak · 2019 to 2026
$2.7M
NIGMS NIH HHS R35 GM133326
6 · The paper itself

Abstract

This study introduces a new class of (NHC)Pd(allyl)Cl complexes featuring thiazol-2-ylidene ligands, which exhibit enhanced steric and electronic properties compared to those of traditional imidazol-2-ylidenes. These air-stable Pd(II)-NHC catalysts demonstrate superior reactivity in chemoselective Suzuki-Miyaura cross-couplings of aryl bromides and amides. Kinetic studies reveal their superior reactivity over traditional imidazol-2-ylidene-based complexes. The findings highlight the potential of thiazole-based carbenes in advancing Pd-catalyzed cross-coupling reactions.

Identifiers

PMID40904284
PMCPMC12461741

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.