ArticleAdvanced synthesis & catalysis2025
Recent Advances in Iodine-Mediated Radical Reactions.
Article in Advanced synthesis & catalysis, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Synthesis of High-Purity Porous Organic Polymers and Exploration of Their Inherent Functionality.ACS applied materials & interfaces · 2026Review
- Novel donor-π-acceptor benzimidazole-based chromophores: synthesis, antitumor assessment, and pharmacokinetics.RSC advances · 2026Article
- Airborne Radioiodine: A Comparative View of Chemical Forms in Medicine, Nuclear Industry, and Fallout Scenarios.International journal of molecular sciences · 2026Review
- Carbene-catalytic enantioselective synthesis of chiral macrocycles.Chemical science · 2025Review
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Authors and funding
4 authors.
Funding
Abstract
Over the past two decades, iodine-mediated free radical reactions have been extensively explored and employed in chemical transformations that complement traditional ionic reactions. In this review, we have updated the progress of the iodine-mediated radical reactions in organic synthesis reported between 2015 and mid-2024, and organized the reactions according to their mechanistic pathways. In general, the proposed mechanisms can be divided into four categories based on the radical initiation or its preceding steps, namely, (1) formation of a covalent X-I (X=C, N, S, Se) bond, which subsequently participates in a radical reaction; (2) formation of a noncovalent N···I bond, which assists the homolysis of the I-I bond; (3) formation of the key iodine radicals by visible-light or heat induced homolysis of I
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Registered trials
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