Evidence map›Paper›PMID 40893257›Full record

ArticleACS omega2025

Electrospinning Versus Solvent Casting Approach to Fabricate Tailored PES/SPES/PVP Membranes of Next Generation.

Giuseppina Scalzo, Nabiollah Gholamiarjenaki, Domenico C Carbone, Concetto Puglisi, Sandro Dattilo, Lorena Saitta, Gholamhossein Sodeifian, Chiara Santillo, Giuseppa Mercorillo, Filippo Samperi

Abstract read
In one paragraph

Article in ACS omega, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Giuseppina ScalzoInstitute for Polymers, Composites and Biomaterials (IPCB) U.O.S. of Catania, CNR, Via P. Gaifami 18, 95126 Catania, Italy.
Nabiollah GholamiarjenakiDepartment of Civil Engineering and Architecture (DICAR), University of Catania, Via Santa Sofia 64, 95125 Catania, Italy.
Domenico C CarboneInstitute for Polymers, Composites and Biomaterials (IPCB) U.O.S. of Catania, CNR, Via P. Gaifami 18, 95126 Catania, Italy.
Concetto PuglisiInstitute for Polymers, Composites and Biomaterials (IPCB) U.O.S. of Catania, CNR, Via P. Gaifami 18, 95126 Catania, Italy.
Sandro DattiloInstitute for Polymers, Composites and Biomaterials (IPCB) U.O.S. of Catania, CNR, Via P. Gaifami 18, 95126 Catania, Italy.ORCID https://orcid.org/0000-0002-3127-9580
Lorena SaittaDepartment of Civil Engineering and Architecture (DICAR), University of Catania, Via Santa Sofia 64, 95125 Catania, Italy.
Gholamhossein SodeifianDepartment of Chemical Engineering, Faculty of Engineering, University of Kashan, 87317-53153 Kashan, Iran.ORCID https://orcid.org/0000-0001-7830-0060
Chiara SantilloInstitute of Polymers, Composites and Biomaterials-CNR, Piazzale E. Fermi 1, 80055 Portici, Italy.
Giuseppa MercorilloInstitute for Polymers, Composites and Biomaterials (IPCB) U.O.S. of Catania, CNR, Via P. Gaifami 18, 95126 Catania, Italy.
Filippo SamperiInstitute for Polymers, Composites and Biomaterials (IPCB) U.O.S. of Catania, CNR, Via P. Gaifami 18, 95126 Catania, Italy.ORCID https://orcid.org/0000-0002-8941-1812

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This study explored the potential of blending poly-(ether sulfone)/disulfonated poly-(ether sulfone) (PES/SPES) at various weight ratios with and without polyvinylpyrrolidone (PVP) to enhance the membrane properties for potential applications like fuel cells, water treatment, and lithium-ion battery separators. SPES was appropriately synthesized as a copolymer constituted of alternated unsulfonated (ES) and disulfonated (SES) sequences, achieving a degree of sulfonation of about 100%. SPES improved the membrane's hydrophilicity, while PVP acts as compatibilizer of PES/SPES blends and pore creator. For comparison purposes, two different approaches were exploited for membrane fabrication: casting and electrospinning techniques. The membranes were characterized using various techniques to evaluate thermal stability, hydrophilicity, uptake behavior, morphology, and microstructure. SEM images revealed that the SPES content and PVP incorporation significantly influenced membrane morphology and porosity. Water uptake increased with SPES content, while methanol uptake was less affected. PVP enhanced both water and methanol uptake in the solvent-cast membranes. Electrospun membranes exhibited higher uptake due to their increased porosity and surface area. Contact angle measurements confirmed that SPES improved hydrophilicity and surface roughness played a crucial role. TGA analysis showed that PES membranes had the highest thermal stability, while SPES decreased it. DSC analysis revealed that PVP acted as a compatibilizer in solvent-cast membranes but not in electrospun ones. The study demonstrated that both blend composition and fabrication techniques could be tailored to optimize membrane properties for specific applications. The findings provide valuable insights for developing advanced membranes with an enhanced performance.

Identifiers

PMID40893257
PMCPMC12392177

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.