Evidence map›Paper›PMID 40890930›Full record

ArticleOrganic letters2025

Fluoranthene-Containing Distorted Nanographenes Exhibiting Two-Photon Absorption Response.

John Bergner, José L Páez, Ermelinda Maçôas, Maria Álvaro-Martins, Jan Borstelmann, Erik Misselwitz, Frank Rominger, Carlos M Cruz, Milan Kivala, Araceli G Campaña

Abstract read
In one paragraph

Article in Organic letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Late-Stage Functionalization of a Hexa-ACS physical chemistry Au · 2026
    Article
  2. A Chiral Saddle-Shaped Nanographene With Two Heptagon-Embedded [4]Helicenes.Angewandte Chemie (International ed. in English) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

John BergnerOrganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
José L PáezDepartment of Organic Chemistry, Faculty of Sciences, Unidad de Excelencia de Química (UEQ), University of Granada, Avda. Fuente Nueva s/n, 18071 Granada, Spain.
Ermelinda MaçôasCentro de Química Estrutural and Institute of Molecular Science, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal.
Maria Álvaro-MartinsCentro de Química Estrutural and Institute of Molecular Science, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal.
Jan BorstelmannOrganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Erik MisselwitzOrganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Frank RomingerOrganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Carlos M CruzDepartment of Organic Chemistry, Faculty of Sciences, Unidad de Excelencia de Química (UEQ), University of Granada, Avda. Fuente Nueva s/n, 18071 Granada, Spain.ORCID 0000-0002-0676-5210
Milan KivalaOrganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.ORCID 0000-0002-4960-4636
Araceli G CampañaDepartment of Organic Chemistry, Faculty of Sciences, Unidad de Excelencia de Química (UEQ), University of Granada, Avda. Fuente Nueva s/n, 18071 Granada, Spain.ORCID 0000-0001-5483-5642

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Two distorted nanographenes combining helicenes and a fluoranthene unit within their polycyclic scaffolds were synthesized. Their structural and electronic properties were elucidated by various spectroscopic methods, and the experimental data were corroborated computationally. The optical and electrochemical properties of the nanographenes were evaluated. The compounds exhibit an improved two-photon absorption cross-section compared to their seven-membered ring-containing counterparts reported previously by us. These results provide important insights into how the incorporation of a pentagonal ring affects two-photon absorption properties of nanographenes. Moreover, one of the nanographenes is chiral and was obtained enantiomerically pure after chiral separation, allowing the study of its chiroptical properties both in absorption (electronic circular dichroism) and emission (circularly polarized luminescence).

Identifiers

PMID40890930
PMCPMC12442070

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.