ArticleAngewandte Chemie (International ed. in English)2025
Rocking (and Shuttling) in a Nanosized Metallobox.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
4 citing papers in PubMed.
- Electronic Activation versus Steric Protection of a Rh(I) Pincer Complex inside a Supramolecular Metallobox.Inorganic chemistry · 2026Article
- Backbone Engineering of Carbon-Centered NHC-Derived Diradicals: From Electronic State Tuning to High-Performance Organic Field-Effect Transistors.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- An Organometallic [2]Catenane With Pt‒(di-NHC)‒Pt Units: A Topology-Driven Strategy for Enhanced Phosphorescence in Discrete Aggregates.Angewandte Chemie (International ed. in English) · 2026Article
- Rocking (and Shuttling) in a Nanosized Metallobox.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
Abstract
Gaining insight into the dynamic behavior of supramolecular systems is essential for understanding selective guest encapsulation and for the rational design of nanodevices capable of precise, controllable motion at the molecular scale. In this work, we report the construction of a pseudo-rotaxane system through the encapsulation of a naphthalenediimide (NDI) derivative bearing long aliphatic chains within the cavity of a nanosized metallorectangle. Electrochemical studies reveal that encapsulation significantly alters the redox properties of the guest. In addition, upon reduction, the NDI-based radical is stably confined within the host cavity, forming a persistent host-guest complex. This encapsulated radical species can be released upon the addition of chloride ions, demonstrating a clear example of reversible, stimuli-responsive guest uptake and release. To elucidate the internal dynamics of the system, we employed variable-temperature
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.