Evidence map›Paper›PMID 40886150›Full record

ArticleChemistry, an Asian journal2025

Stimuli-Responsive Supramolecular Polymers of Mono- and Bis-triazolylphenylazoaniline-Functionalized Copillar[5]Arenes: With Distinctive Binding Modes.

Chun-Yi Yao, Yung-Yu Chang, Reguram Arumugaperumal, Tzu-Yi Chao, Putikam Raghunath, Ming-Chang Lin, Wen-Sheng Chung

Abstract read
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In one paragraph

Article in Chemistry, an Asian journal, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Chun-Yi YaoDepartment of Applied Chemistry, National Chiao Tung University, Hsinchu, 30050, Taiwan.
Yung-Yu ChangDepartment of Applied Chemistry, National Chiao Tung University, Hsinchu, 30050, Taiwan.
Reguram ArumugaperumalDepartment of Applied Chemistry, National Chiao Tung University, Hsinchu, 30050, Taiwan.ORCID https://orcid.org/0000-0001-8279-1798
Tzu-Yi ChaoDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu, 30050, Taiwan.
Putikam RaghunathDepartment of Applied Chemistry, Center for Interdisciplinary Molecular Science, National Yang Ming Chiao Tung University, Hsinchu, 30010, Taiwan.
Ming-Chang LinDepartment of Applied Chemistry, Center for Interdisciplinary Molecular Science, National Yang Ming Chiao Tung University, Hsinchu, 30010, Taiwan.
Wen-Sheng ChungDepartment of Applied Chemistry, National Chiao Tung University, Hsinchu, 30050, Taiwan.ORCID https://orcid.org/0000-0003-0134-9725

Funding

Ministry of Science and Technology, Taiwan MOST-110-2113-M-A49-009Ministry of Science and Technology, Taiwan MOST-111-2113-M-A049-023National Science and Technology Council NSTC-112-2113-M-A049-010National Science and Technology Council NSTC-113-2113-M-A049-017
6 · The paper itself

Abstract

Mono- and bis-triazolylphenylazoaniline-functionalized copillar[5]arenes 1 and 2 were synthesized forming linear supramolecular polymers with dual pH and photo responsiveness. Upon acidification, copillar[5]arene 1 undergoes protonation, converting its aniline group into a primary ammonium ion (1-H), which significantly enhances its supramolecular polymerization compared to 1. Designed as an AB-type supramolecular polymer, 1-H exhibits distinct polymerization behavior in contrast to neutral copillar[5]arene 2, which forms a 1:1 supramolecular polymer with dimethoxypillar[5]arene (DMP5). Copillar[5]arene 2 is believed to bind DMP5 through its cavity, linking two aniline groups from separate molecules to form a two component supramolecular polymer. The degree of polymerization of 1-H and the 1:1 ratio of 2 and DMP5 can be controlled by adjusting the pH, as confirmed by pH- and concentration-dependent

Indexed as

AzobenzeneClick reactionsCopillar[5]arenesSelf‐assemblyStimuli responsiveSupramolecular polymers

Identifiers

PMID40886150
PMCPMC12584021

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.