ArticlePrecision chemistry2023
Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation.
Article in Precision chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Lewis Acid/Base Au-Mn Pairs in Metal Nanoclusters for Enhanced Photocatalytic C(spAngewandte Chemie (International ed. in English) · 2026Article
- Copper Nanoclusters with Exposed Active Sites for Highly Efficient Protoboration of C-C Multiple Bonds.Molecules (Basel, Switzerland) · 2026Article
- Atomically Precise Fcc-Amorphous Homometal Heterojunction with ∼1 nm Size.Precision chemistry · 2025Article
- Whole-Process Precision Chemistry for Clusters.Precision chemistry · 2024Article
- Planar Core and Macrocyclic Shell Stabilized Atomically Precise Copper Nanocluster Catalyst for Efficient Hydroboration of C-C Multiple Bond.Journal of the American Chemical Society · 2024Article
- NIR-II emissive anionic copper nanoclusters with intrinsic photoredox activity in single-electron transfer.Nature communications · 2024Article
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The emergence of metal nanoclusters with atomically precise compositions and structures provides an opportunity for in-depth investigation of catalysis mechanisms and structure-property correlations at the nanoscale. However, a serious problem for metal nanocluster catalysts is that the ligands inhibit the catalytic activity through deactivating the surface of the nanoclusters. Here, we introduce a novel catalytic mode for metal nanoclusters, in which the nanoclusters initiate the catalysis via single electron transfer (SET) without destroying the integrity of nanoclusters, providing a solution for the contradiction between activity and stability of metal nanoclusters. We illustrated that the novel activation mode featured low catalyst loading (0.01 mol %), high TOF, mild reaction conditions, and easy recycling of catalyst in alkyne hydroborylation, which often suffered from poor selectivity, low functional group tolerance, etc. Furthermore, the catalyst [Au
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