ArticleJACS Au2025
Beyond Surface-Localized Reaction Paradigm: Intramacropore-Confined Thermal-Field-Driven Photothermal Reactivity Leap.
Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
1 citing paper in PubMed.
- A universal photothermal recycling strategy for post-consumer plastics using bio-derived porous carbon.Nature communications · 2026Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Although photothermal reactions have gained extensive attention, their surface-localized naturewhere heat concentrates on nanoscale surfacesleads to suboptimal chemical reactivity. This study establishes an intrapore-confined thermal-field-driven reaction paradigm with unprecedented photothermal reactivity, through investigations of photothermal Congo Red (CR) pyrolysis in three-dimensional ordered macroporous carbon (OMC) versus nonmacroporous solid carbon (SC). Two model systems are constructed: (1) intrapore-confined configuration: fluorine-cerium nanodomains with ultrahigh CR adsorption capacity are anchored onto macroporous walls to achieve uniform CR distribution in OMC; (2) surface-localized pathway: CR is blended on the external surface of SC, decoupling intrapore confinement and surface localization mechanisms. The intrapore-confined system demonstrates transformative advantages: near-complete CR pyrolysis (>99.00 vs 39.89%), a 27.73-fold increase in rate constants (4.00 vs 0.14%/s), and a 30.71-fold enhancement in energy efficiency. Finite element analysis reveals an intrapore-confined thermal field within OMC due to its low thermal conductivity. Characterized by an inward-increasing temperature gradient, this field overcomes surface-localized limitations by reconstructing the temperature distribution, forming effective reaction driving forces. This work transcends conventional understanding of photothermal mechanisms and highlights macroporous architecture as a critical design principle for advanced photothermal materials.
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Registered trials
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