ArticleJACS Au2025
Design and Synthesis of 3‑Amino-4-azidoethoxyfurazan: A Supramolecular Energetic Material with Insensitivity Properties.
Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
High-performance insensitive energetic materials have long been a central focus of energetic materials research. To effectively balance high energy density and insensitivity, a structure-based screening was performed using the Cambridge Crystallographic Data Centre database. Consequently, a strategy enhancing the stability of energetic compounds through supramolecular assembly based on self-complementary hydrogen bonding was developed. Guided by this approach, a novel energetic compound, 3-amino-4-azidoethoxyfurazan (AAeF), was designed and synthesized successfully. Single-crystal X-ray diffraction analysis revealed the formation of two pairs of self-complementary hydrogen bonds within AAeF, which adopt a zigzag arrangement, resulting in a supramolecular structure characterized by rigid "plate-like" and flexible "chain-like" configurations. This structure, containing the "Fz-NH
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