ArticleThe journal of physical chemistry. B2025
Theoretical Modeling of the Redox Thermodynamics of Nucleic Acid Building Blocks in the Condensed Phase.
Article in The journal of physical chemistry. B, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Low-energy solvated electrons can be captured by nitrogenous bases and localized on the nucleic acid to form a stable anion. The interaction between electrons and the bases is related to alterations in the stability and function of nucleic acids. Here, we report the theoretical-computational estimates of the adiabatic electron affinities (AEAs) and the reduction potentials of the nucleobases in solution. Our data show that pyrimidine bases exhibit the highest tendency to form stable anions in both the gas phase and condensed phases (water and
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