ArticleNature communications2025
In situ synthesis of copper-based mordenite for nitrogen/methane sieving.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Photocatalytic Cascade Nitrogen Fixation for Selective Purification of Methane-Rich Coal-Bed Gas Over a Bimetallic MOF.Angewandte Chemie (International ed. in English) · 2026Article
- Evaluation of Ag-, Fe- and Ni-exchanged mordenite for the reduction of 4-nitrophenol under different reduction pathways.RSC advances · 2026Article
- In situ synthesis of copper-based mordenite for nitrogen/methane sieving.Nature communications · 2025Article
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Authors and funding
9 authors.
Funding
Abstract
Achieving low-energy and high-efficiency sieving of nitrogen rejection from methane in natural gas purification processes requires precise control of material pore size with a resolution of 0.1-0.2 Å, which is highly challenging. Here, we report a novel adsorbent (MOR-Cu), a mordenite with copper introduced in situ via high-temperature crystallization, enabling precise sieving of nitrogen and methane by the appropriate pore size and pore geometry. Refinement of the crystal structure shows that the higher crystallization temperature changes the position of the copper component, increasing pore volume and enhancing nitrogen adsorption capacity and kinetics. MOR-Cu-210 obtained by crystallization at 210 °C exhibits a record nitrogen adsorption capacity (0.74 mmol g
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