Evidence map›Paper›PMID 40875285›Full record

ReviewChemistry, an Asian journal2025

Catalytic Reactions Involving the Oxidative Addition of Si─Halogen and Si─Pseudohalogen Bonds as a Key Step.

Naoto Chatani

Abstract readReview
In one paragraph

Review in Chemistry, an Asian journal, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

1 author.

Naoto ChataniDepartment of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan.ORCID https://orcid.org/0000-0001-8330-7478

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The oxidative addition of C-halogen bonds of aryl halides or alkyl halides is a critical step in a wide variety of transition-metal-catalyzed C─C and C-heteroatom bond formation reactions. In contrast, the oxidative addition of Si-halogen bonds of halosilanes has not been used in the development of transition metal-catalyzed reactions, although halosilanes are known to be highly reactive in many organic reactions with oxygen-containing compounds. However, recent progress in transition metal-catalyzed reactions using halosilanes has resulted in several synthetically useful and revolutionary methodologies concerning organosilicon synthesis through the oxidative addition of Si-halogen bonds, even less reactive Si─Cl bonds. This review will focus on transition metal-catalyzed reactions of C─C multiple bonds, such as alkenes, alkynes, and 1,3-dienes with R

Indexed as

Cross‐CouplingCross‐Electrophile CouplingHalosilanesOxidative additionSilylmetalation

Identifiers

PMID40875285
PMCPMC12533345

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.